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J. Phys.: Condens. Matter 6 (1994) pp. L613-L618
Surface states as probes of buried impurities
Cavendish Laboratory, Madingley Road, Cambridge CB3 0HE, United Kingdom
Abstract
Shockley surface states at metal surfaces decay exponentially into
the crystal, typically penetrating several interplanar spacings.
Within this distance defects such as impurity atoms will scatter
the surface state electrons and give rise to characteristic standing
wave patterns in the local density of states outside the surface,
similar to those recently detected with the STM due to scattering
by adatoms. A multiple scattering theory is developed to model
this situation and applied to impurities near the Cu(111) surface.
The results are discussed within a two-dimensional scattering model
and the prospects for observation with the STM considered.