TY - CONF T1 - Dielectric properties of hydroxyapatite based ceramics A1 - Gittings,J.P. A1 - Bowen,C.R. A1 - Turner,I.G. A1 - Dent,A.C.E. A1 - Baxter,F.R. A1 - Chaudhuri,J.B. Y1 - 2008/// KW - Bioceramics KW - Dielectric KW - Hydroxyapatite KW - Polarization KW - Sintering SP - 157 EP - 160 JF - 4M2008 - Fourth International Conference on Multi-Material Micro Manufacturing T2 - 4M2008 - Fourth International Conference on Multi-Material Micro Manufacturing A2 - Dimov,S. A2 - Menz,W. CY - Scotland PB - Whittles Publishing T3 - 4M Network of Excellence N2 - This paper studies the ac conductivity and permittivity of hydroxyapatite based ceramics (HA) at temperatures from room temperature to 1000°C. HA ceramics were prepared either as dense ceramics or in porous form with interconnected porosity and were sintered in either air or water vapour. Samples were thermally cycled to examine the influence of surface adsorbed water on conductivity and permittivity. Surface bound water was thought to contribute to conductivity for both dense and porous materials at temperature below 200°C. At temperatures below 700§C the permittivity and ac conductivity of HA was also influenced by the degree of dehydration and thermal history. At higher temperatures (700-1000°C), bulk ionic conduction was dominant and activation energies are in the range of ~2eV, indicating that hydroxyl ions are responsible for conductivity. SN - 978-1904445-76-0 Y2 - 2008/10/09/ M2 - Cardiff, UK ER -